Publikationen von Maurice van Gastel

Depenbrock, F.; Bill, E.; van Gastel, M.; SantaLucia, D. J.; Walleck, S.; Oldengott, J.; Stammler, A.; Glaser, T.: Activation of Electrophilic Reactivity by Protonation and Oxidation of a Peroxo Co^IIICo^III Complex: Reactivity and Molecular Structures of Hydroperoxo, Superoxo, and Peroxo Co^IIICo^III Complexes. Journal of the American Chemical Society 147 (7), S. 5775 - 5784 (2025)

Spinnato, D.; Nöthling, N.; Leutzsch, M.; van Gastel, M.; Wagner, L.; Neese, F.; Cornella, J.: A trimetallic bismuth(I)-based allyl cation. Nature Chemistry 17, S. 265 - 270 (2025)

Wahl, I. M.; Sengupta, K.; van Gastel, M.; Decamps, L.; DeBeer, S.: Understanding the P-Cluster of Vanadium Nitrogenase: an EPR and XAS Study of the Holo vs. Apo Forms of the Enzyme. ChemBioChem: A European Journal of Chemical Biology 26 (3), e202400833 (2025)

Debnath, S.; Laxmi, S.; McCubbin Stepanic, O.; Quek, S. Y.; van Gastel, M.; DeBeer, S.; Krämer, T.; England, J.: A Four-Coordinate End-On Superoxocopper(II) Complex: Probing the Link between Coordination Number and Reactivity. Journal of the American Chemical Society 146 (34), S. 23704 - 23716 (2024)

Rütter, D.; van Gastel, M.; Leutzsch, M.; Nöthling, N.; SantaLucia, D.; Neese, F.; Fürstner, A.: Molybdenum(VI) Nitrido Complexes with Tripodal Silanolate Ligands. Structure and Electronic Character of an Unsymmetrical Dimolybdenum μ-Nitrido Complex Formed by Incomplete Nitrogen Atom Transfer. Inorganic Chemistry 63 (18), S. 8376 - 8389 (2024)

Depenbrock, F.; Limpke, T.; Bill, E.; SantaLucia, D. J.; van Gastel, M.; Walleck, S.; Oldengott, J.; Stammler, A.; Bögge, H.; Glaser, T.: Reactivities and Electronic Structures of μ-1,2-Peroxo and μ-1,2-Superoxo Co^IIICo^III Complexes: Electrophilic Reactivity and O₂ Release Induced by Oxidation. Inorganic Chemistry 62 (43), S. 17913 - 17930 (2023)

Mao, W.; Zhang, Z.; Fehn, D.; Jannuzzi, S. A. V.; Heinemann, F. W.; Scheurer, A.; van Gastel, M.; DeBeer, S.; Munz, D.; Meyer, K.: Synthesis and Reactivity of a Cobalt-Supported Singlet Nitrene. Journal of the American Chemical Society 145 (25), S. 13650 - 13662 (2023)

Pang, Y.; Nöthling, N.; Leutzsch, M.; Kang, L.; Bill, E.; van Gastel, M.; Reijerse, E.; Goddard, R.; Wagner, L.; SantaLucia, D. J. et al.; DeBeer, S.; Neese, F.; Cornellà, J.: Synthesis and isolation of a triplet bismuthinidene with a quenched magnetic response. Science 380 (6649), S. 1043 - 1048 (2023)

Merschel, A.; Rottschäfer, D.; Neumann, B.; Stammler, H.-G.; Ringenberg, M.; van Gastel, M.; Demirer, I.; Andrada, D. M.; Ghadwal, R. S.: Crystalline Anions Based on Classical N-Heterocyclic Carbenes. Angewandte Chemie International Edition 62 (5), e202215244 (2023)

Pang, Y.; Nöthling, N.; Leutzsch, M.; Kang, L.; Bill, E.; van Gastel, M.; Reijerse, E.; Goddard, R.; Wagner, L.; SantaLucia, D. et al.; DeBeer, S.; Neese, F.; Cornella, J.: A “non-magnetic” triplet bismuthinidene enabled by relativity. ChemRxiv: the Preprint Server for Chemistry (2022)

Mao, W.; Fehn, D.; Heinemann, F. W.; Scheurer, A.; van Gastel, M.; Jannuzzi, S. A. V.; DeBeer, S.; Munz, D.; Meyer, K.: Umpolung in a Pair of Cobalt(III) Terminal Imido/Imidyl Complexes. Angewandte Chemie International Edition 61 (36), e202206848 (2022)

Chatterjee, S.; Harden, I.; Bistoni, G.; Castillo, R. G.; Chabbra, S.; van Gastel, M.; Schnegg, A.; Bill, E.; Birrell, J. A.; Morandi, B. et al.; Neese, F.; DeBeer, S.: A Combined Spectroscopic and Computational Study on the Mechanism of Iron-Catalyzed Aminofunctionalization of Olefins Using Hydroxylamine Derived N–O Reagent as the “Amino” Source and “Oxidant”. Journal of the American Chemical Society 144 (6), S. 2637 - 2656 (2022)

Quek, S. Y.; Debnath, S.; Laxmi, S.; van Gastel, M.; Krämer, T.; England, J.: Sterically Stabilized End-On Superoxocopper(II) Complexes and Mechanistic Insights into Their Reactivity with O–H, N–H, and C–H Substrates. Journal of the American Chemical Society 143 (47), S. 19731 - 19747 (2021)

Haack, A.; Hillenbrand, J.; van Gastel, M.; Fürstner, A.; Neese, F.: Spectroscopic and Theoretical Study on Siloxy-Based Molybdenum and Tungsten Alkylidyne Catalysts for Alkyne Metathesis. ACS Catalysis 11 (15), S. 9086 - 9101 (2021)

Schulz, C. E.; van Gastel, M.; Pantazis, D. A.; Neese, F.: Converged Structural and Spectroscopic Properties for Refined QM/MM Models of Azurin. Inorganic Chemistry 60 (10), S. 7399 - 7412 (2021)

Haack, A.; Hillenbrand, J.; Leutzsch, M.; van Gastel, M.; Neese, F.; Fürstner, A.: Productive Alkyne Metathesis with “Canopy Catalysts” Mandates Pseudorotation. Journal of the American Chemical Society 143 (15), S. 5643 - 5648 (2021)

Sharma, M. K.; Rottschäfer, D.; Neumann, B.; Stammler, H.-G.; Danés, S.; Andrada, D. M.; van Gastel, M.; Hinz, A.; Ghadwal, R. S.: Metalloradical Cations and Dications Based on Divinyldiphosphene and Divinyldiarsene Ligands. Chemistry – A European Journal 27 (18), S. 5803 - 5809 (2021)

Hillenbrand, J.; van Gastel, M.; Bill, E.; Neese, F.; Fürstner, A.: Isolation of a Homoleptic Non-Oxo Mo(V) Alkoxide Complex: Synthesis, Structure and Electronic Properties of Penta-tert-Butoxymolybdenum. Journal of the American Chemical Society 142 (38), S. 16392 - 16402 (2020)

Lin, Y.-H.; Kutin, Y.; van Gastel, M.; Bill, E.; Schnegg, A.; Ye, S.; Lee, W.-Z.: A Manganese(IV)-Hydroperoxo Intermediate Generated by Protonation of the Corresponding Manganese(III)-Superoxo Complex. Journal of the American Chemical Society 142 (33), S. 10255 - 10260 (2020)

Sharma, M. K.; Blomeyer, S.; Neumann, B.; Stammler, H.-G.; Hinz, A.; van Gastel, M.; Ghadwal, R. S.: Isolation of singlet carbene derived 2-arsa-1,3-butadiene radical cations and dications. Chemical Communications 56 (24), S. 3575 - 3578 (2020)